1. Zgrabik, J. C.; Bhuniya, B.; Branstad Phillips, T.; Barroso, J.; Vlaisavljevich, B.; Daly, S. R. "Volatile Lanthanide Complexes with Fluorinated Heptadentate Ligands." Dalton Trans. 2024, accepted.
  1. Zgrabik, J. C.; Bhowmick, R.; Eckstrom, F. D.; Harrison, R. A.; Fetrow, T. V.; Blake, A. V.; Vlaisavljevich, B.; Daly, S. R. "Comparative Study of Alkyl Substituent and Metal Size on the Structures of Trivalent f-Element Phosphinodiboranates." Inorg. Chem. 2023, ASAP (link).
  1. Fetrow, T. V.;* Zgrabik, J.;* Bhowmick, R.; Eckstrom, F. D.; Crull, G.; Vlaisavljevich, B.; Daly, S. R. "Quantifying the Influence of Covalent Metal-Ligand Bonding on Differing Solution Reactivity of Trivalent Uranium and Lanthanide Complexes." Angew. Chem., Int. Ed. 2022, 61, e202211145 (link). *Equal contributions.
  1. Skaria, M.; Culpepper, J. D.; Daly, S. R. "Leveraging Metal and Ligand Reactive Sites for One Pot Reactions: Ligand-Centered Borenium Ions for Tandem Catalysis with Palladium." Chem. Eur. J. 2022, 28, e202201791 (link).
  1. Culpepper, J. D.; Lee, K.; Portis, W.; Swenson, D. C.; Daly, S. R. "Fluorination and Hydrolytic Stability of Water-Soluble Platinum Complexes with a Borane-Bridged Diphosphoramidite Ligand." Dalton Trans. 2022, 51, 12895-12903 (link).
  1. Spielvogel, K. D.; Durgaprasad, G.; Daly, S. R. "Configurational Flexibility of a Triaryl-Supported SBS Ligand with Rh and Ir: Structural Investigations and Olefin Isomerization Catalysis." Organometallics 2022, 41, 1344–1352 (link).
  1. Daly, S. R.; Bellott, B. J.; McAlister, D. R.; Horwitz, E. P.; Girolami, G. S. "Pr(H3BNMe2BH3)3 and Pr(thd)3 as Volatile Carriers for Actinium-225. The Deposition of Actinium-Doped Praseodymium Boride Thin Films for Potential Use in Brachytherapy." Inorg. Chem. 2022, 61, 7217–7221 (link).
  1. Culpepper, J. D.; Lee, K.; Daly, S. R. "Modular Synthesis of Diphosphoramidite Ligands Derived from 1,8,10,9-Triazaboradecalin and Their Complexes with Ni, Pd, and Pt." Polyhedron 2022, 221, 115877 (link).
  1. Spielvogel, K. D.;* Stumme, N. C.;* Fetrow, T. V.; Wang, L.; Luna, J. A.; Keith, J. M.; Shaw, S. K.; Daly, S. R. "Quantifying Variations in Metal-Ligand Cooperative Binding Strength with Cyclic Voltammetry and Redox-Active Ligands." Inorg. Chem. 2022, 61, 2391–2401 (link). *Equal contributions.
  1. Grzybowski, S.; Daly, S. R. "6.09 - Organometallic Pincer Complexes With Group 6 Metals." In Comprehensive Organometallic Chemistry IV, Parkin, G., Meyer, K., O’hare, D. Eds.; Elsevier, 2022, 648-694 (link).
  1. Daly, S. R. "5.01 - Overview and Introduction to Volumes 5 and 6." In Comprehensive Organometallic Chemistry IV, Parkin, G., Meyer, K., O’hare, D. Eds.; Elsevier, 2022, 1 (link).
  1. Fetrow, T. V.; Daly, S. R. "Mechanochemical Synthesis and Structural Analysis of Trivalent Lanthanide and Uranium Diphenylphosphinodiboranates." Dalton Trans. 2021, 50, 11472–11484 (link).
  1. Fetrow, T. V.; Grabow, J. P.; Leddy, J.; Daly, S. R. "Convenient Syntheses of Trivalent Uranium Starting Materials without Uranium Metal." Inorg. Chem. 2021, 60, 7593–7601 (link).
  1. Meyer, R. L.; Greer, S. M.; Blake, A. V.; Cary, S. K.; Ditter, A. S.; Daly, S. R.; Li, F.; Kozimor, S. A.; Matson, E. M.; Mocko, V.; Seidler, G. T.; Stein, B. W.; Weinstein, S. D. "Characterizing Polyoxovanadate‐Alkoxide Clusters Using Vanadium K‐Edge X‐Ray Absorption Spectroscopy." Chem. Eur. J. 2021, 27, 1592–1597 (link).
  1. Lee, K.; Lai, P.; Parveen, R.; Donahue, C. M.; Wymore, M. M.; Massman, B. A.; Vlaisavljevich, B.; Teets, T. S.; Daly, S. R. "Modifying the Luminescent Properties of a Cu(I) Diphosphine Complex Using Ligand-Centered Reactions in Single Crystals." Chem. Commun. 2020, 56, 9110-9113 (link). Invited submission for Emerging Investigators Issue.
  1. Spielvogel, K. D.;* Luna, J. A.;* Loria, S. M.; Weisburn, L. P.; Stumme, N. C.; Ringenberg, M. R.; Durgaprasad, G.; Keith, J. M.; Shaw, S. K.; Daly, S. R. "The Influence of Multisite Metal-Ligand Cooperativity on the Redox Activity of Noninnocent N2S2 Ligands." Inorg. Chem. 2020, 59, 10845–10853 (link). *Equal contributions.
  1. Lee, K.; Culpepper, J. D.; Parveen, R.; Swenson, D. C.; Vlaisavljevich, B.; Daly, S. R. "Modifying Phosphorus(III) Substituents to Activate Remote Ligand-Centered Reactivity in Triaminoborane Ligands." Organometallics 2020, 39, 2526–2533 (link).
  1. Fetrow, T. V.; Bhowmick, R.; Achazi, A. J.; Blake, A. V.; Eckstrom, F. D.; Vlaisavljevich, B.; Daly, S. R. "Chelating Borohydrides for Lanthanides and Actinides: Structures, Mechanochemistry, and Case Studies with Phosphinodiboranates." Inorg. Chem. 2020, 59, 48-61 (link). Invited Forum article for special issue on Innovative f-Element Chelating Strategies.
  1. Spielvogel, K. D.; Coughlin, E. J.; Petras, H.; Luna, J. A.; Benson, A.; Donahue, C. M.; Kibasa, A.; Lee, K.; Salacinski, R.; Bart, S. C.; Shaw, S. K.; Shepherd, J.; Daly, S. R. "The Influence of Redox-Innocent Donor Groups in Tetradentate Ligands Derived from o-Phenylenediamine: Electronic Structure Investigations with Nickel." Inorg. Chem. 2019, 58, 12756-12774 (link).
  1. Lee, K.; Blake, A. V.; Donahue, C. M.; Spielvogel, K. D.; Bellott, B. J.; Daly, S. R. "Quantifying the Interdependence of Metal-Ligand Covalency and Bond Distance using Ligand K-edge XAS." Angew. Chem., Int. Ed. 2019, 58, 12451-12455 (link).
  1. Goodwin, A. P. C.;* Jing, S.;* Albrecht-Schmitt, T. E.; Blake, A. V.; Batista, E. R.; Daly, S. R.; Dehnen, S.; Evans, W. J.; Gaunt, A. J.; Kozimor, S. A.; Lichtenberger, N.; Scott, B. L.; Yang, P. " [Am(C5Me4H)3], an Organometallic Am3+ Complex." Angew. Chem., Int. Ed. 2019, 58, 11695-11699 (link). *Equal contributions.
  1. Lee, K.;* Blake, A. V.;* Tanushi, A.; McCarthy, S. M.; Kim, D.; Loria, S. M.; Donahue, C. M.; Spielvogel, K. D.; Keith, J. M.; Daly, S. R.; Radosevich, A. T. " Validating the Biphilic Hypothesis of Nontrigonal P(III) Compounds." Angew. Chem., Int. Ed. 2019, 58, 6993-6998 (link). *Equal contributions.
  1. Lee, K.; Kim, C.; Buckley, J. L.; Vlaisavljevich, B.; Daly, S. R. " Isolation of Ligand-Centered Borocations in Molybdenum Complexes Containing a Triaminoborane-Bridged Diphosphorus Ligand." Dalton Trans. 2019, 48, 3777-3785 (link). Invited submission for themed web collection: Inorganic Chemistry of the p-Block Elements.
  1. Bennett, K. T.; Bone, S. E.; Akin, A. C.; Birnbaum, E. R.; Blake, A. V.; Brugh, M.; Daly, S. R.; Engle, J. W.; Fassbender, M. E.; Ferrier, M. G.; Kozimor, S. A.; Lilley, L. M.; Martinez, C. A.; Mocko, V.; Nortier, F. M.; Stein, B. W.; Thiemann, S. L.; Vermeulen, C. "Large-Scale Production of 119mTe and 119Sb for Radiopharmaceutical Applications." ACS Central Sci. 2019, 5, 494-505 (link). Highlight: Albrecht-Schmitt, T. E. "The Paradox of Using Radionuclides to Treat Disease." ACS Central Sci. 2019, 5, 383-385 (link).
  1. Lee, K.; Kirkvold, C.; Vlaisavljevich, B.; Daly, S. R. "Ligand-Centered Borenium Reactivity in Triaminoborane-Bridge Diphosphine Complexes." Inorg. Chem. 2018, 57, 13188-13200 (link).
  1. Lee, K.; Wei, H.; Blake, A. V.; Donahue, C. M.; Keith, J. M.; Daly, S. R. "Measurement of Diphosphine σ-Donor and π-Acceptor Properties in d0 Titanium Complexes Using Ligand K-edge XAS and TDDFT." Inorg. Chem. 2018, 57, 10277-10286 (link).
  1. Blake, A. V.;* Fetrow, T. V.;* Theiler, Z. J.; Vlaisavljevich, B.; Daly, S. R. "Homoleptic Uranium and Lanthanide Phosphinodiboranates." Chem. Commun. 2018, 5602-5605 (link). *Equal contributions.
  1. Daly, S. R. "Actinide Borohydrides." In The Heaviest Metals: Science and Technology of the Actinides and Beyond; Hanusa, T. P. and Evans, W. J., Eds.; 2018, John Wiley & Sons, Ltd: West Sussex, UK (link).
  1. Blake, A. V.; Wei, H.; Lee, K.; Donahue, C. M.; Keith, J. M.; Daly, S. R. "Solution and Solid Ligand K-edge XAS Studies of PdCl2 Diphosphine Complexes with Phenyl and Cyclohexyl Substituents." Eur. J. Inorg. Chem. 2018, 2267-2276 (link). Highlighted as a cover feature for the 20th Anniversary Issue and designated a VIP article. 
  1. Donahue, C. M.; Daly, S. R. "Ligand K-edge XAS Studies of Metal-Phosphorus Bonds: Applications, Limitations, and Opportunities." Comments Inorg. Chem. 2018, 38, 54-78. (link). Invited review.
  1. Finn, M. T.; Donahue, C. M.; Blake, A. V.; An. N.; Daly, S. R.; Voutchkova-Kostal, A. M. "Electronic Support Effects of Tunable Mixed Oxides on Immobilized Palladium N-Heterocyclic Carbene Complexes." Eur. J. Inorg. Chem. 2018, 2471-2479 (link).
  1. Blake, A. V.; Wei, H.; Donahue, C. M.; Lee, K.; Keith, J. M.; Daly, S. R. "Solid Energy Calibration Standards for P K-edge XANES: Electronic Structure Analysis of PPh4Br." J. Synchrotron Radiat. 2018, 25, 529-536 (link).
  1. Durgaprasad, G; Luna, J., A.; Spielvogel, K. D.; Haas, C.; Shaw, S. K.; Daly, S. R. "Ru(II) Complexes with a Chemical and Redox-Active S2N2 Ligand: Structures, Electrochemistry, and Metal-Ligand Cooperativity." Organometallics 2017, 36, 4020-4031 (link).
  1. Lee, K.; Donahue, C. M.; Daly, S. R. "Triaminoborane-Bridged Diphosphine Complexes with Ni and Pd: Coordination Chemistry, Structures, and Ligand-Centered Reactivity." Dalton Trans. 2017, 46, 9394-9406 (link).
  1. Lee, K.; Wei, H.; Blake, A. V.; Donahue, C. M.; Keith, J. M.; Daly, S. R. "Ligand K-edge XAS, DFT, and TDDFT Analysis of Pincer Linker Variations in Rh(I) PNP Complexes: Reactivity Insights from Electronic Structure." Dalton Trans. 2016, 45, 9774-9785 (link). Invited submission and selected for the cover of the "New Talent: Americas" Issue.
  1. Donahue, C. M.; McCollum, S. P.; Forrest, C. M.; Blake, A. V.; Bellott, B. J.; Keith, J. M.; Daly, S. R. "Impact of Coordination Geometry, Bite Angle, and Trans Influence on Metal–Ligand Covalency in Phenyl-Substituted Phosphine Complexes of Ni and Pd." Inorg. Chem. 2015, 54, 5646-5659 (link).

Before Iowa

  1. Caroff, C. M.; Bellott, B. J.; Daly, C. I.; Daly, S. R.; Dunbar, A. C.; Mallek, J. L.; Nesbit, M. A.; Girolami, G. S. “Sodium Aminodiboranates Na(H3BNR2BH3): Structural and Spectroscopic Studies of Steric and Electronic Substituent Effects.” Inorg. Chem. 2022, 61, 18412-18423 (link).

  1. Chang, N. N.; Daly, S. R.; Girolami, G. S. “ Salt Elimination Reactions Do Not Always Eliminate. Mechanistic Study of the Reaction of NdCl3 with Sodium N,N-Dimethylaminodiboranate.” Polyhedron 2019, 162, 52-58 (link). Invited Submission for Special Issue in Honor of Bill Jones.

  1. Macor, J. A; Brown, J. J.; Cross, J. N.; Daly, S. R.; Gaunt, A. J.; Girolami, G. S.; Janicke, M. T.; Kozimor, S. A.; Neu, M. P.; Olson, A. C.; Reilly, S. D.; Scott, B. L. "Coordination Chemistry of 2,2′-Biphenylenedithiophosphinate and Diphenyldithiophosphinate with U, Np, and Pu." Dalton Trans. 2015, 44, 18923-18936 (link).

  1. Olson, A. C.; Keith, J. M.; Batista, E. R.; Boland, K. S.; Daly, S. R.; Kozimor, S. A.; MacInnes, M. M.; Martin, R. L.; Scott, B. L. "Using solution- and solid-state S K-edge X-ray absorption spectroscopy with density functional theory to evaluate M–S bonding for MS42− (M = Cr, Mo, W) dianions." Dalton Trans. 2014, 43, 17283-17295 (link).

  1. Donahue, C. M.; Lezama Pacheco, J. S.; Keith, J. M.; Daly, S. R. “Sulfur K-edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory of Arsenic Dithiocarbamates.” Dalton Trans. 2014, 43, 9189-9201 (link).

  1. Donahue, C. M.; Black, C. M.; Pecnik, S. L; Savage, T. R.; Scott, B. L; Daly, S. R. “Synthesis, Characterization and Structural Comparisons of Phosphonium and Arsenic Dithiocarbamates with Alkyl and Phenyl Substituents.” Polyhedron 2014, 75, 110-117 (link).

  1. Wen, X. D.; Löble, M. W.; Batista, E. R.; Bauer, E.; Boland, K. S.; Burrell, A. K.; Conradson, S. D.; Daly, S. R.; Kozimor, S. A.; Minasian, S. G.; Martin, R. L; McCleskey, T. M; Scott, B. L; Shuh, D. K; Tyliszczak, T. “Electronic structure and O K-edge XAS spectroscopy of U3O8.” J. Electron Spectrosc. 2014, 194, 81-87 (link). Invited Submission for Special Issue in Honor of Richard Martin.

  1. Minasian, S. G.; Keith, J. K.; Batista, E. R.; Boland, K. S.; Bradley, J. A.; Daly, S. R.; Kozimor, S. A.; Lukens, W. W.; Martin, R. L.; Nordlund, D.; Seidler, G. T.; Shuh, D. K.; Sokara, D.; Tyliszczak, T.; Wagner, G. L.; Weng, T.; Yang, P. “Covalency in Metal-Oxygen Bonds Evaluated using Oxygen K-edge Spectroscopy and Electronic Structure Theory.” J. Am. Chem. Soc. 2013, 135, 1864-1871 (link).

  1. Shaista, B.; Kumar, N.; Zhang, P.; Daly, S. R.; Dunbar, A. C.; Girolami, G. S.; Abelson, J. R. “Growth Inhibitors to Enhance Nucleation Density in Thin Film Chemical Vapor Deposition.” Chem. Mat. 2013, 25, 662-667 (link).

  1. Vlaisavljevich, B.; Miro, P.; Koballa, D.; Todorova, T. K.; Daly, S. R.; Girolami, G. S.; Cramer, C. J.; Gagliardi, L. “Volatilities of Actinide and Lanthanide N,N-Dimethylaminodiboranate Chemical Vapor Deposition Precursors: A DFT Study.” J. Phys. Chem. C 2012, 116, 23194-23200 (link).

  1. Daly, S. R.; Keith, J. M.; Batista, E. R.; Boland, K. S.; Clark, D. L; Kozimor, S. A.; Martin, R. L. “S K-edge XAS and TDDFT of Dithiophosphinate Extractants: Minor Actinide Selectivity and Electronic Structure Correlations.” J. Am. Chem. Soc. 2012, 134, 14408-14422 (link).

  1. Schmucker, S. W.; Kumar, N.; Abelson, J. R.; Daly, S. R.; Girolami, G. S.; Bischof, M. R.; Jaeger, D. L.; Reidy, R. F.; Gorman, B. P.; Alexander, J.; Ballard, J. B.; Randall, J. N.; Lyding, J. W. “Field-directed sputter sharpening for tailored probe materials and atomic-scale lithography.” Nature Commun. 2012, 3, 1907/1-1907/8 (link).

  1. Daly, S. R.; Keith, J. M.; Batista, E. R.; Boland, K. S.; Kozimor, S. A.; Martin, R. L.; Scott, B. L. “Probing Ni[S2PR2]2 Electronic Structure to Generate Insight Relevant to Minor Actinide Extraction Chemistry.” Inorg. Chem. 2012, 51, 7551-7560 (link).

  1. Daly, S. R.; Kim, D. Y.; Girolami, G. S. “Lanthanide N,N-Dimethylaminodiboranates as a New Class of Highly Volatile Chemical Vapor Deposition Precursors.” Inorg. Chem. 2012, 51, 7050-7065 (link).

  1. Daly, S. R.; Bellott, B. J.; Nesbit, M. A.; Girolami, G. S. “Synthesis and Structural Diversity of Barium N,N-Dimethylaminodiboranates.” Inorg. Chem. 2012, 51, 6449-6459 (link).

  1. Daly, S. R.; Boland, K. S.; Klaehn, J. R.; Kozimor, S. A.; Peterman, D. R.; Scott, B. L. “NMR Spectroscopy and Structural Characterization of Dithiophosphinates Relevant to Minor Actinide Extraction Processes.” Dalton Trans. 2012, 41, 2163-2175 (link).

  1. Daly, S. R.; Ephritikhine, M.; Girolami, G. S. “Crystal Structure and Spectroscopic Study of the Uranium Oxo Complex U2(μ-O)(BH4)6(dme)2 (dme = 1,2-dimethoxyethane) and Reformulation of U2(μ-H)2(BH4)6(dme)2.” Polyhedron 2012, 33, 41-44 (link).

  1. Kraft, S. J.; Williams, U. J.; Daly, S. R.; Schelter, E.; Kozimor, S. A.; Boland, K. S.; Kikkawa, J. M.; Forrest, W. P.; Christensen, C. N.; Schwarz, D. E.; Fanwick, P. E.; Clark, D. L.; Conradson, S. D.; Bart, S. C. “The Synthesis, Characterization, and Multi-Electron Reduction Chemistry of Uranium Supported by Redox-Active α-Diimine Ligands.” Inorg. Chem. 2011, 50, 9838-9848 (link).

  1. Piccoli, P. M. B.; Schultz, A. J.; Todorova, T. K.; Gagliardi, L.; Daly, S. R.; Girolami, G. S. “Big Metals, Small Ligands: Characterization of the 15-Coordinate Complex Thorium Aminodiboranate [Th(H3BN(CH3)2BH3)4] by Single Crystal Neutron Diffraction,” Am. Cryst. Assn. Symp. Trans. 2010, TR.01.3 (link).

  1. Daly, S. R.; Bellott, B. J.; Kim, D. Y.; Girolami, G. S. “Synthesis of the Long-Sought Unsubstituted Aminodiboranate Na(H3BNH2BH3) and its N-Alkyl and N,N-Dialkyl Analogs.” J. Am. Chem. Soc. 2010, 132, 7254-7255 (link).

  1. Daly, S. R.; Girolami, G. S. “Synthesis, Characterization, and Structures of Divalent Europium and Ytterbium N,N-Dimethylaminodiboranates.” Inorg. Chem. 2010, 49, 4578-4585 (link).

  1. Daly, S. R.; Girolami, G. S. “Synthesis, Characterization, and Structures of Uranium(III) N,N-Dimethylaminodiboranate Complexes.” Inorg. Chem. 2010, 49, 5157-5166 (link).

  1. Daly, S. R.; Kim, D. Y.; Yang, Y.; Abelson, J. R.; Girolami, G. S. “Lanthanide N,N-Dimethylaminodiboronates: Highly Volatile Precursors for the Deposition of Lanthanide-Containing Thin Films.” J. Am. Chem. Soc. 2010, 132, 2106-2107 (link).

  1. Daly, S. R.; Piccoli, P. M. B.; Schultz, A. J.; Todorova, T. K.; Galgliardi, L.; Girolami, G. S. “Synthesis and Properties of a Fifteen-Coordinate Complex: The Thorium Aminodiboranate [Th(H3BNMe2BH3)4].” Angew. Chem. Intl. Ed. 2010, 49, 3379-3381 (link).

  1. Ye, W.; Peña Martin, P. A.; Kumar, N.; Daly, S. R.; Rockett, A. A.; Abelson, J. R.; Girolami, G. S.; Lyding, J. W. “Direct Writing of Sub-5 nm Hafnium Diboride Metallic Nanostructures.” ACS Nano 2010, 4, 6818-6824 (link).

  1. Daly, S. R.; Girolami, G. S. “Uranium-Hydrogen Interactions: Synthesis and Crystal Structures of Tris(N,N-dimethylaminodiboranato)uranium(III).” Chem. Commun. 2010, 46, 407-408 (link).

  1. Kumar, N.; Yanguas-Gil, A.; Daly, S. R.; Girolami, G. S.; Abelson, J. R. “Remote Plasma Treatment of Si Surfaces: Enhanced Nucleation in Low-Temperature Chemical Vapor Deposition.” Appl. Phys. Lett. 2009, 95, 144107/1-144107/3 (link).

  1. Kumar, N.; Noh, W.; Daly, S. R.; Girolami, G. S.; Abelson, J. R. “Low Temperature Chemical Vapor Deposition of Hafnium Nitride-Boron Nitride Nanocomposite Films.” Chem. Mat. 2009, 21, 5601-5606 (link).

  1. Kumar, N.; Yanguas-Gil, A.; Daly, S. R.; Girolami, G. S.; Abelson, J. R. “Growth Inhibition to Enhance Conformal Coverage in Thin Film CVD.” J. Am. Chem. Soc. 2008, 130, 17660-17661 (link).